These two phrases are interesting because they involve the same noun, albeit in different cases, and different forms of the same verb.
Deus Vult means "God wills (it)." It was first used as a rallying cry in 1096 during the First Crusade. Deus is the subject of the sentence and is in the nominative singular case. Vult is third person singular present indicative of volo, velle, volui, which is the verb to want.
Deo Volente means "God willing" and is the Latin equivalent of the Arabic inshallah. Deo is in the ablative case. Volente is the ablative case of the present participle volens of the verb volo, velle, volui. The phrase is an ablative absolute in which the participle is in agreement with the noun in the ablative case. The term absolute means that the phrase is independent of the rest of the sentence.
Deo volente is sometimes abbreviated d.v..